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by Fabio Seime

How Micro-Hybrid’s NDIR Technology Redefines Refrigerant Gas Detection

Refrigerant gas detection requires reliable performance across low leak concentrations and high exposure levels. Micro-Hybrid’s NDIR sensor technology uses an innovative multiple-reflection optical design to measure ammonia and other refrigerants precisely, even within compact sensor geometries. The result is a stable alternative to electrochemical sensing for demanding refrigeration and industrial safety applications.

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Moving Beyond Electrochemical and Catalytic Limitations

Monitoring refrigerant gases in industrial cooling is critical for personnel safety and plant efficiency. While optical infrared sensing is well established for modern fluorinated refrigerants (HFCs, HFOs), ammonia (NH₃) has long been one of the most challenging gases to measure using compact infrared technology. As a result, much of the market has relied on electrochemical sensing.

Electrochemical sensors became widely adopted due to their availability and familiarity. However, their limitations are well known. Operation depends on electrodes, membranes, and ongoing chemical reactions, making them inherently sensitive to aging, humidity, contamination, poisoning, and cross-gas interference. Cross-sensitivity, in particular, is difficult to eliminate completely and must often be managed through compensation strategies.


Why Has NH₃ Been Difficult for NDIR?

NDIR technology offers a fundamentally stable sensing principle and is widely used across various refrigerant absorption bands. However, ammonia presents unique optical challenges compared with standard refrigerants. NH₃ has relatively low absorption around its relevant absorption band near 10.5 µm, while compact infrared sources provide only limited optical output in this spectral region. In conventional straight-path optical designs, the combination of low source intensity and limited NH₃ absorption can result in signals that are too small for reliable detection within compact sensor geometries.


A New Optical Approach

Micro-Hybrid addresses these limitations through an advanced multiple-reflection optical design. This approach significantly increases the effective optical path length within a compact form factor. The resulting signal enhancement enables reliable detection across refrigerant-specific absorption bands - including the difficult 10.5 µm NH₃ region - without relying on chemical reactions, high operating temperatures, or large sensor housings.

Beyond ammonia, Micro-Hybrid NDIR technology supports the measurement of a broad range of refrigerant gases used in commercial and industrial cooling systems. This includes common fluorinated refrigerants such as HFCs and HFOs, as well as natural refrigerants including CO₂ and hydrocarbons. Each gas has characteristic infrared absorption bands, enabling targeted optical measurement with the appropriate emitter, optical path, filter configuration, and detector. This gives system developers a flexible foundation for building leak-detection and process-monitoring solutions across multiple refrigeration platforms.


A New Performance Benchmark

The resulting NDIR sensor platform delivers performance characteristics that are difficult to achieve with electrochemical technologies:

  • Wide measurement range: 0–30,000 ppm, supporting trace detection and high-concentration industrial environments.
  • High sensitivity: detection limit ≤ 30 ppm at zero point.
  • Fast response: T90 < 30 seconds for real-time monitoring.
  • Fine resolution: 1 ppm digital resolution.
  • Strong focus on accuracy: high measurement precision is critical for gas detection systems, where dependable alarm behavior matters more than simply maximizing operating lifetime.
  • Excellent stability: long-term drift ≤ ±450 ppm per year.
  • Strong linearity: ≤ ±300 ppm across the measurement range.
  • Reliable repeatability: ≤ ±150 ppm.

Case Study: Measuring Refrigerants with NDIR vs. Electrochemical Sensors

Selecting a refrigerant sensor affects far more than the measurement range. In refrigeration and industrial safety systems - whether monitoring synthetic blends, hydrocarbons, CO₂, or ammonia - sensor technology influences alarm reliability, maintenance requirements, environmental robustness, and the long-term consistency of measured values.

Electrochemical sensors are established and widely used for toxic refrigerants like NH₃. They measure gas through chemical reactions involving electrodes, electrolyte, membranes, and gas diffusion structures. This can provide a familiar and cost-effective solution, but the signal depends on the condition of the sensor’s internal chemistry.

Over time, aging, humidity, contamination, and exposure to high gas concentrations can influence sensor behavior. Cross-sensitivity to other gases may also require compensation measures. In safety-related applications, this can make regular verification, calibration, and replacement planning particularly important.

Micro-Hybrid’s NDIR gas sensors take a different approach. They measure refrigerant gases optically through infrared absorption at gas-specific wavelengths, without relying on consumable sensing chemistry. The multiple-reflection optical design increases the effective optical path inside a compact housing, enabling a sufficiently strong signal even in the challenging NH₃ absorption region near 10.5 µm.

Evaluation criterion Electrochemical gas sensor Micro-Hybrid NDIR refrigerant sensor
Measurement principle Chemical reaction Infrared absorption
Consumable components Electrodes, membranes, and electrolyte age over time No consumable sensing chemistry
Environmental effects Can be affected by humidity, contamination, and poisoning Stable optical measurement principle
Cross-sensitivity May require compensation for interfering gases Wavelength-based measurement supports improved selectivity
Measurement range Varies by sensor model 0–30,000 ppm
Detection limit Varies by sensor model ≤ 30 ppm at zero point
Response time Varies by sensor model T90 < 30 seconds
Long-term drift Influenced by chemical aging ≤ ±450 ppm per year
Typical service concept Regular replacement and recalibration Typical lifetime exceeds 7 years; calibration remains recommended

Example: Refrigeration Plant Gas Detection

In a refrigeration machinery room, a gas detection system must identify small leaks early while also remaining dependable during a major gas release. Whether managing traditional fluorinated refrigerants or natural alternatives like ammonia and CO₂, the measurement must remain stable despite changes in ambient temperature, humidity, and general industrial conditions.

The Micro-Hybrid NDIR platform combines a ≤ 30 ppm detection limit with a 0–30,000 ppm measurement range, allowing one sensor architecture to cover early leak detection and high-concentration monitoring. Its T90 response time of less than 30 seconds supports timely alarm handling, while 1 ppm digital resolution enables precise concentration reporting.

For system developers, the main advantage is an optical measurement principle designed for stable, repeatable performance without the aging mechanisms associated with electrochemical sensing. The compact 32 mm diameter and 16.8 mm height, together with analog and digital interfaces, support seamless integration into existing gas detection architectures across diverse refrigerant monitoring setups. Electrochemical sensors remain a familiar solution, but NDIR offers a compelling alternative where long-term measurement stability, accurate alarm thresholds, and resistance to chemical sensor aging are key requirements.


Built for Industrial Use

The sensor is engineered for durability in demanding environments. Service life can reach up to 10 years, with a typical lifetime exceeding 7 years. Operation does not rely on consumable chemistry, reducing common degradation mechanisms.

Resistance to overloading and automatic fault detection support reliable operation under challenging conditions. Stable performance is maintained across a wide environmental range:

  • Temperature: -40 to +60 °C
  • Pressure: 700 to 1200 hPa
  • Humidity: up to 95% RH, non-condensing

The Fundamental Advantage of NDIR

NDIR measures gas concentration through infrared absorption at gas-specific optical wavelengths rather than chemical reactions. This approach provides intrinsic selectivity across various refrigerant molecules, eases cross-sensitivity risks, and supports stable measurement performance without consumable materials.

Applications

The sensor platform is suited for demanding gas-monitoring tasks across the refrigeration cycle, including:

  • Industrial refrigeration machinery rooms and cold storage (NH₃, CO₂, fluorinated blends)
  • Commercial HVAC/R chiller monitoring and leak detection
  • Industrial process gas monitoring and leak containment
  • Semiconductor manufacturing and cleanroom chemical safety

For refrigeration safety-system developers in particular, this combination of optical precision, compact retrofit-friendly design, and robust signal quality supports accurate, dependable refrigerant monitoring across both natural and synthetic gases.

A New Generation of Optical Refrigerant Sensing

Micro-Hybrid’s optical sensing technology enables high-performance refrigerant detection including difficult target gases like ammonia with capabilities that are difficult to achieve with traditional technologies. It represents a shift toward stable, high-precision gas sensing for demanding industrial environments and refrigeration safety applications.

Moving beyond consumable electrochemical sensors gives developers access to a stable optical measurement principle, dependable accuracy, analog and digital integration options, and consistent long-term performance. Whether an application requires trace-level leak detection, high-concentration monitoring, or reliable alarm handling across industrial refrigeration systems, the Micro-Hybrid NDIR platform provides a robust foundation designed for precision and practical system integration.

Discuss Your Application with Our Experts

Every refrigerant monitoring application has specific requirements regarding target gas, measurement range, detection limit, interfaces, and environmental conditions. Our application experts will help you evaluate the right NDIR sensor configuration and support its integration into your system.

Sang Cai T +49 36601 592 139

Noah Bleeck T +49 36601 592 292

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